Effective adsorption of bisphenol A from aqueous solution using phosphoric acid-assisted hydrochar.

Sycamore leaf biochar (PSAC) was prepared by a two-step phosphoric acid-assisted hydrothermal carbonization combined with a short-time activation method. The characterization results showed that the introduction of phosphoric acid molecules and thermal activation resulted in a substantial increase in the specific surface area (994.21 m2/g) and microporous capacity (0.307 cm3/g) of PSAC. The batch adsorption results showed that the adsorption process of PSAC on bisphenol A (BPA) was best described by the pseudo-second-order kinetic model and Sips isothermal model, with a maximum adsorption capacity of 247.42 mg/g. The adsorption of BPA onto PSAC was determined to be a spontaneous endothermic process. The equilibrium adsorption capacity of PSAC exhibited an upward trend with increasing initial BPA concentration and temperature while decreasing with higher adsorbent dosage and pH value. Coexisting cations and humic acids in water have little impact on the adsorption performance of PSAC for BPA. The adsorption mechanism of BPA by PSAC was mainly governed by pore filling and hydrogen bonding interactions, π-π interactions, and intraparticle diffusion. Furthermore, PSAC demonstrated good reusability by its sustained adsorption capacity of BPA, which remained at 82.6% of the initial adsorption capacity even after four adsorption-desorption cycles. These findings highlight the potential of utilizing low-cost sycamore leaf biochar as an effective adsorbent for the removal of the endocrine disruptor BPA.

Effective immobilization of bisphenol A utilizing activated biochar incorporated into soil: combined with batch adsorption and fixed-bed column studies.

This study presented the mixture of biochar and soil for removal of bisphenol A (BPA) to assess environmental remediation ability. Using phoenix tree leaves as biomass and phosphoric acid as activator, after one-step hydrothermal and short-term activation, the eventual solid product was phosphoric acid hydrothermal activated carbon (HPC). The characterizations showed that HPC had the high specific surface (994.21 m2·g-1), and large unsaturated esters and hydroxyl groups. The saturated adsorption capacities of batch and column adsorption for the addition of 0.5% HPC to soil were 0.790 mg·g-1 and 67.23 mg·kg-1, while to the natural soil were 0.236 mg·g-1 and 8.75 mg·kg-1, respectively. The adsorption kinetics and thermodynamic analysis indicated that the adsorption process utilizing HPC incorporated into soil was a chemical reaction rate-controlled, physical-dominated multilayer adsorption, and spontaneous endothermic. Also, batch adsorption experiments and analysis were performed under different pH levels, HPC contents, organic acid concentrations, and cationic strengths. Successively, fixed-bed column experiments were carried out with and without the HPC; the results showed that the wide mass transfer zone led to the effective fixation of BPA, and the organic acid had no obvious effect on the fixation of BPA when the 1.0% HPC mixed with soil. Finally, through characterizations and data analysis, the enhanced adsorption of BPA by HPC mixed with soil mainly relied on π-π interaction, hydrogen bonding, followed by electrostatic attraction and pore filling.